In the past, we have had several customers who are concerned about the use of sulphites in our winemaking process. In an attempt to clear up any misunderstandings, here are a few facts about sulphites that you should know.
Potassium Metabisulphite is a stable source of sulfites in winemaking. Sulphites work by releasing free sulfur dioxide, which inhibits yeast, mold and bacteria. It does this in two ways: one, it kills some of the organisms outright, and two, it blocks the surviving organisms' ability to reproduce.
To help prevent oxidation, sulphites are also added directly to wine after fermentation. Wine oxidation follows the same pattern that you see in the cut edge of an apple - the wine turns brown and takes on a flat cardboard taste. Sulfur binds with the oxygen in wine and prevents this damage.
Many people worry that they may be allergic to sulphites in wine. True sulphite allergies are very rare. It's very likely that most people have been exposed to much higher levels of sulphites in the past. In the 1970's for example, restaurants would douse their salad bars with 2000 PPM (parts per million) sulphite solution in order to keep the produce fresh. Mixing this with acidic foods, such as salad dressings or vinegar, would cause the salad to release clouds of sulphite gas, provoking unpleasant reactions.
What most people describe as a wine headache or a sulphite headache is actually a reaction to bio-amines in the wine. Bio-amines are compounds formed in wines for various reasons, one of the most common being malolactic fermentation in the presence of sugar. In this process, malolactic bacteria is added to (primarily) red wines to soften the wine by converting the harsher Malic acid into the more mellow tasting Lactic acid (like in yogurt). This makes the wines drinkable at a much younger age. The large amounts of bio-amines produced by this process provoke the allergic reactions some people have to red wines and some whites such as malolactic-affected Chardonnays. Wines made from wine kits never go through malolactic fermentation and thus will not give headaches to those who respond negatively to malolactic commercial wines.
This is not to say that sulphites are totally benign. People with asthma or emphysema should avoid inhaling sulphite powder or the gas that comes off the prepared solution. It can act as a bronchial constrictor, aggravating any existing breathing problems.